With the rapid development of 4G network and the Internet, OTT video and live video outbreak rapidly, the mobile video business has gradually become the most important flow entry, so we need a series of indicators to measure video service performance over 4G mobile network. Current main method is based on the quality of service (QoS) and the quality of experience (QoE). QoS does not take into account users’ subjective opinion and fail to measure video quality and user experience effectively. The approach based on the QoE involves the user subjective factor while watching video and objective factor, which can reflect user mobile video experience effectively. This paper studies the influence of wireless parameters, video quality, playback quality and terminal parameters on the mobile video experience, establishes the mobile video experience evaluation model based on Analytic Hierarchy Process(AHP), and developed the video experience evaluation software VideoMos based on the ijkplayer video player framework and accuracy rate reached 71.57%, with a certain reference value.